What should a new analyst ask in a first one-to-one with the head of reward?

I start on Monday as a reward analyst at a 4,000-person engineering consultancy in Leeds. It is my second job; I spent two years as an HR data analyst at a hospital trust, so I know reporting but very little about reward itself.

The head of reward has put a 45-minute one-to-one in my diary for day two and asked me to bring questions. I do not want to waste it on things I could find on the intranet.

What would you ask if you were me? And what would you, as a manager, be pleased to be asked?